TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.100 INTRODUCTION
Section 232.100 Introduction
This Part establishes a program
to identify toxic air contaminants. This Part includes a list of toxic air
contaminants (Section 232.Appendix A), the procedures to determine a toxic air
contaminant and the procedures to amend the list.
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.110 INCORPORATIONS BY REFERENCE
Section 232.110
Incorporations by Reference
a) The following materials are incorporated by reference:
American Conference of Governmental Industrial Hygienists
(ACGIH). Threshold Limit Values and Biological Exposure Indices for 1989-90
(1989). Document can be obtained from: 6500 Glenway Avenue, Building D-7,
Cincinnati, Ohio 45211-4438.
Good Laboratory Practice Standards, 21 CFR 58 (1990).
Good Laboratory Practice Standards, 40 CFR 160 (1989).
Good Laboratory Practice Standards, 40 CFR 792 (1990).
Organization for Economic Co-operation and Development
(OECD). OECD Guidelines For Testing of Chemicals, Appendix: Good Laboratory
Practice [c(81)30(Final)] (November, 1989). Document can be obtained from:
OECD Publications and Information Centre, 2001 L Street, N.W., Suite 700,
Washington, D.C. 20036-4095.
United States Department of Health and Human Services, Public
Health Service, National Toxicological Program (NTP). Fifth Annual Report on
Carcinogens (1989). Document can be obtained from: National Technical
Information Service, 5285 Port Royal Road, Springfield, Virginia 22161.
World Health Organization, International Agency for Research
on Cancer (IARC). Monographs on the Evaluation of Carcinogenic Risks to
Humans, Overall Evaluations of Carcinogenicity: An Updating of IARC Monographs
Volumes 1 to 42, Supplement 7 (1987). Document can be obtained from: WHO
Publications Centre USA, 49 Sheridan Avenue, Albany, New York 12210.
b) This Section incorporates no future editions or amendments.
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.120 DEFINITIONS
Section 232.120 Definitions
The definitions of 35 Ill. Adm.
Code 201 and 211 apply to this Part, as well as the definitions contained in
this Section. Where a definition contained in this Section is more specific
than those found in 35 Ill. Adm. Code 201 and 211, it must take precedence in
application of this Part.
"ACGIH"
means the American Conference of Governmental Industrial Hygienists.
"Adverse
health effect" means a health injury or disease that may be produced by
exposure to a contaminant. This includes any decrement in the function of an
organ or organ system or any subclinical organ lesion that is likely to lead to
a decrement in an organ or organ system function.
"Commercial
fuel" means:
Any fuel
offered for final sale for use in combustion processes;
Any gaseous or
liquid fuel generated as a by-product at a source for which the source has been
issued an operating permit to use such fuel internally in combustion processes,
including internal combustion engines; or
Any waste
derived fuel for which an operating permit has been issued and which represents
no more than five percent (.05) by weight on a daily basis of total fuel used
in combustion processes by a source.
"Critical
gestation days" means the days during which the formation and
differentiation of organs and organ systems occurs during embryonic
development.
"Fugitive
emissions" is defined according to 35 Ill. Adm. Code 203.1190.
"IARC"
means the World Health Organization's International Agency for Research on
Cancer.
"IRIS"
means the USEPA's Integrated Risk Information System.
"Illinois
Toxic Air Contaminant" (ITAC) means any toxic air contaminant listed under
35 Ill. Adm. Code 232, excluding, specifically: coke oven gas; any hazardous
air pollutant (HAP) now or hereafter listed under Section 112(b) of the Clean
Air Act (CAA) (1990); and any pollutant or contaminant listed as a compound of
concern under the Great Waters and Coastal Waters Program under Section 112(m)
of the CAA.
"ITAC
Source Report" means the report that the Agency provides to the source
that lists data fields for the information required in the emissions report for
Subpart D of this Part, and contains the information, if any, that previously
has been reported to the Agency for those data fields.
"LC50"
means the concentration in the air of a contaminant that kills, or is estimated
to kill, 50% (.50) of a population of laboratory animals where the exposure is
brief (8 hours or less) and where the route of exposure is inhalation.
"LD50"
means the dose of a contaminant that kills, or is estimated to kill, 50% (.50)
of a population of laboratory animals where the route of exposure is ingestion.
"Lowest
observed adverse effect level" means the lowest experimentally determined
dose at which a statistically or biologically significant indication of the
toxic effect of concern is observed.
"Manufacture"
means, for the purposes of Subpart D of this Part, to produce, prepare, or
compound a listed ITAC, and includes coincidental production of an ITAC (e.g.,
as a by-product or impurity) as a result of the manufacture, processing or
otherwise use or treatment of one or more chemical substances not an ITAC. An
ITAC intentionally incorporated into a product is considered to be
manufactured.
"NTP"
means the United States Department of Health and Human Services, Public Health
Services' National Toxicological Program.
"No
observed effect" means the condition where no adverse health effect has
been detected.
"Otherwise
use" means, for the purposes of Subpart D of this Part, any activity
involving a listed ITAC at a source that does not fall within the definition of
"manufacture" or "process."
"Process"
means, for the purposes of Subpart D of this Part, the preparation of an ITAC
after its manufacture for distribution in commerce in the same physical state
as, or in a different form or physical state from, that in which it was
received by the source, or preparation that produces a change in physical state
or chemical form.
"Toxic
air contaminant" (TAC) means a contaminant identified under Section
232.200 or Section 232.501 of this Part and listed in Appendix A of this Part.
(Source: Amended at 49 Ill. Reg. 6462, effective April 23, 2025)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.130 APPLICABILITY
Section 232.130
Applicability
The requirements of this Part do
not apply to the following:
a) Retail dry cleaning operations;
b) Retail and noncommercial storage and handling of motor
fuels;
c) Combustion processes using only commercial fuel, including
internal combustion engines; and
d) Incidental or minor sources including laboratory-scale
operations, and such other sources or categories of sources which are
determined by the Board to be of minor significance. (Section 9.5(e) of
the Act)
SUBPART B: DETERMINATION OF A TOXIC AIR CONTAMINANT
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.200 CHARACTERISTICS FOR DETERMINING A TOXIC AIR CONTAMINANT
Section 232.200
Characteristics for Determining a Toxic Air Contaminant
a) Contaminants found by the Board to be Toxic Air Contaminants
pursuant to subsections (b) or (c), below, shall be listed in Appendix A.
b) A Toxic Air Contaminant is a contaminant which the
Board finds may cause or significantly contribute to an increase in
mortality or an increase in serious irreversible or incapacitating reversible
illness, or may pose a significant threat to human health. (Section 9.5(c)
of the Act)
c) The Board shall find that a contaminant is a Toxic Air
Contaminant upon a determination that:
1) The contaminant has a Toxicity Score of 3 or greater using the
procedures for determining the Toxicity Score described in Section 232.310; or
2) The contaminant is classified as a carcinogen according to
Section 232.320; and
3) The contaminant meets the statutory definition set forth in
subsection (b), above.
d) Any person can petition the Board to list or delist a toxic
air contaminant pursuant to the requirements of Section 232.500. The Board
will consider such a petition a proposal for rulemaking subject to the
requirements of 35 Ill. Adm. Code 102.
SUBPART C: PROCEDURES FOR EVALUATING CHARACTERISTICS OF A TOXIC AIR CONTAMINANT
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.300 PURPOSE
Section 232.300 Purpose
This Subpart identifies the
procedures used to evaluate the characteristics of a toxic air contaminant.
The Agency will use these procedures in proposing to list or delist toxic air
contaminants in Section 232.Appendix A.
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.310 PROCEDURES FOR DETERMINING THE TOXICITY SCORE
Section 232.310 Procedures
for Determining the Toxicity Score
The Toxicity Score is the sum of
the Acute Lethality Score and the Chronic Toxicity Score. The Acute Lethality
Score is a number which indicates a contaminant's potential to cause death.
The Chronic Toxicity Score is a number which indicates a contaminant's
potential to cause adverse health effects after chronic exposure.
a) Procedure for Determining the Acute Lethality Score
1) The Acute Lethality Score is derived from toxicological
studies using laboratory rats. One of two routes of exposure is used:
inhalation or ingestion. Values derived from inhalation are used in preference
to values derived from ingestion.
2) The Acute Lethality Score is derived from the following table:
|
Inhalation Concentration
(LC50)
|
Acute
Lethality Score
|
|
|
|
|
Less than: 500 mg/cu. m
|
3
|
|
500-4,999 mg/cu. m
|
2
|
|
5,000-50,000 mg/cu. m
|
1
|
|
Greater than: 50,000 mg/cu. m
|
0
|
or, if the above data are not available:
|
Ingestion Dose (LD50)
|
Acute
Lethality Score
|
|
|
|
|
Less than: 500 mg/kg
|
3
|
|
500-499 mg/kg
|
2
|
|
500-5,000 mg/kg
|
1
|
|
Greater than: 5,000 mg/kg
|
0
|
b) Procedure for Determining the Chronic Toxicity Score
The Chronic
Toxicity Score is the product of the Lowest Toxic Dose Score and the Severity
of Effects Score.
1) Procedure for Determining the Lowest Toxic Dose Score
The Lowest
Toxic Dose Score is a number based upon the lowest dose of a contaminant that
causes an observable adverse health effect. The Lowest Toxic Dose Score is
derived from the following table:
|
Dose
|
Lowest
Toxic Dose Score
|
|
|
|
Less than: 5 mg/kg
|
1
|
|
5-50 mg/kg/day
|
⅔
|
|
Greater than: 50 mg/kg/day
|
⅓
|
|
|
|
2) Procedure for Determining the Severity of Effects Score
The Severity
of Effects Score is a number based upon the category of organ(s) affected and
the level of effect upon the organ(s).
A) Organ Categories
There are
three categories of organs or organ systems which are identified as follows:
i) Category I includes: organs, the impairment or loss of which
is fatal or usually cannot be compensated for by the body; gonads, the loss of
which prevents the transmission of genetic material; and, adverse reproductive
outcome including stillbirth, miscarriage, or reduced litter size (animal
studies). The Category I organs are: Lungs, Heart, Brain, Spinal Cord,
Kidneys, Liver, Bone Marrow, and Gonads.
ii) Category II includes: organs, the impairment or loss of
which may be fatal, but which can be compensated for by drug or replacement
therapy; adverse effect on an immune function which may be life threatening;
changes in the composition or function of blood constituents which may be life
threatening; and, certain fetotoxic effects including premature birth, reduced
birth weight, and reduced morphometric parameters. The Category II organs
are: Adrenals, Thyroids, Parathyroids, Pituitary, Pancreas, Esophagus,
Stomach, Small Intestine, Large Intestine, Lymph Nodes, Thymus, Trachea.
iii) Category III includes: organs, the impairment or loss of
which is not life threatening but may result in functional or emotional
handicaps; adverse effect on an immune function which is not life threatening;
changes in composition or function of blood which are not life threatening but
may result in functional handicaps. Category III organs include, but are not
limited to: Oviducts, Epididymides, Uterus, Prostrate, Seminal Vesicles,
Ductus Deferens, Penis, Vagina, Eyes, Bone, Nose, Peripheral Nerves, Muscles,
Urinary Bladder, Blood Vessels, Ears, Gallbladder, Larynx, Mammary Glands,
Salivary Glands, Skin, Spleen, Tongue, Teeth, Ureter, Urethra, Pharynx.
B) Levels of Effect
There are four
levels of effect: Serious Irreversible ("SI"); Serious Reversible
("SR"); Non-serious Irreversible ("NI"); and Non-serious
Reversible ("NR").
i) A serious effect is an incapacitating condition or a
condition which significantly contributes to an increase in mortality.
ii) A non-serious effect is a non-incapacitating condition or a
condition which is unlikely to contribute to an increase in mortality.
iii) An irreversible effect is one that is permanent or would
require medical treatment to correct.
iv) A reversible effect is a temporary effect.
C)
Table of Severity of Effects Scores
The Severity
of Effects Score for any level of effect observed in an organ belonging to a
specified organ category is derived from the following table:
|
|
|
Organ
Category
|
|
|
|
I
|
II
|
III
|
|
|
|
|
|
|
|
Level of Effect
|
SI
|
6
|
5
|
4
|
|
|
SR
|
5
|
4
|
3
|
|
|
NI
|
4
|
3
|
2
|
|
|
NR
|
3
|
2
|
1
|
|
|
|
|
|
|
|
No Observed Effect
|
|
0
|
0
|
0
|
D) When a study identifies an adverse health effect on multiple
organs within the same category at the lowest observed adverse effect level,
the Severity of Effects Score is increased by a value of 1. In no event can
the Severity of Effects Score be greater than 6.
3) Additional procedures for calculating the Chronic Toxicity
Score are described in Section 232.Appendix B.
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.320 CARCINOGEN CLASSIFICATION
Section 232.320 Carcinogen
Classification
a) For purposes of this Part, the Agency will consider a
contaminant to be a carcinogen if it is classified in the following manner:
1) A Category A1 or A2 Carcinogen by AGCIH; or
2) A Category 1 or 2A/2B Carcinogen by IARC; or
3) A "Human Carcinogen" or "Anticipated Human
Carcinogen" by NTP; or
4) A Category A or B1/B2 Carcinogen by the United States
Environmental Protection Agency (USEPA) in IRIS or a Final Rule issued in a
Federal Register notice by the USEPA as of the effective date of this regulation.
b) The references ACGIH, IARC, and NTP are incorporated by
reference in Section 232.110. The reference IRIS is the United States
Environmental Protection Agency, Office of Health and Environmental Assesment,
Integrated Risk Information System. The categories A, B1, and B2 carcinogens
of IRIS as of December 31, 1989, are listed in Section 232.Appendix C.
SUBPART D: SOURCE IDENTIFICATION AND REPORTING REQUIREMENTS
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.400 PURPOSE
Section 232.400 Purpose
This Subpart establishes
identification and reporting requirements for new and existing sources that
emit Illinois Toxic Air Contaminants.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.410 APPLICABILITY
Section 232.410
Applicability
a) This Subpart shall apply to any owner or operator of a source
that manufactures, processes or imports 25,000 lbs. or more of any individual
ITAC in any calendar year or otherwise uses 10,000 lbs. of any individual ITAC
in any calendar year.
b) This Subpart shall not apply to the following:
1) Retail dry cleaning operations;
2) Retail and noncommercial storage and handling of motor fuels;
3) Combustion processes, including internal combustion engines,
using only commercial fuel;
4) Equipment and operations which are exempt from permitting
requirements pursuant to 35 Ill. Adm. Code 201.146;
5) Components of commercial and non-commercial agrichemical
facility operations that are permitted under 8 Ill. Adm. Code 255 by the
Department of Agriculture and endorsed by the Illinois Environmental Protection
Agency pursuant to Section 39.4 of the Act; [415 ILCS 5/39.4.]
6) Farm storage or application of agriculture chemicals and
distribution facilities not covered by 8 Ill. Adm. Code 255 that are used for
storage or distribution of agrichemicals; and
7) The requirements of this Subpart shall not apply to the
application of registered pesticides.
c) If an ITAC is present in a mixture of chemicals at a source at
a concentration below 1% (0.01) by weight, or .1% (0.001) by weight in the case
of an ITAC which is a carcinogen listed in Appendix C of this Part, an owner or
operator subject to this Subpart is not required to consider the quantity of
the ITAC in such mixture when determining whether an applicable threshold has
been met under subsection (a) of this Section or in determining the amount of
emissions to be reported under Section 232.430 of this Part.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.420 ITAC SOURCE REPORT
Section 232.420 ITAC Source
Report
a) On or before July 1, 1997, the Agency shall provide to the
owner or operator of a source that is expected to be subject to this Subpart
the ITAC Source Report. The ITAC Source Report shall contain all data fields
for the information required under this Subpart.
b) The information on emissions provided by the owner or operator
of a source in the emissions report submitted pursuant to Section 232.430 of
this Part shall be based on the best information available to the owner or
operator and that is reflective of the operations of the source and its ITAC
emissions.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.421 EMISSIONS REPORT CERTIFICATION
Section 232.421 Emissions
Report Certification
All emission reports filed
pursuant to this Subpart shall contain the following certification statement:
"I hereby certify that I have reviewed the attached documents and that, to
the best of my knowledge and belief, the submitted information is true and complete
and that the amounts and values in this report are accurate based on reasonable
estimates using data available to the preparers of this report." The
certification statement shall be signed by an individual responsible for the
certification of the accuracy of the emissions report who will take legal
responsibility for the information verified or reported therein. The
certification statement shall be accompanied by the full name, title, actual
signature, date of signature, and a telephone number of the individual signing
the emissions report.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.423 FAILURE TO RECEIVE AN ITAC SOURCE REPORT
Section 232.423 Failure to
Receive an ITAC Source Report
Failure to receive the ITAC
Source Report from the Agency shall not relieve an owner or operator from the
obligation to file a complete emissions report. Any owner or operator who does
not receive the ITAC Source Report on or before July 1, 1997, may contact the
Agency to request the ITAC Source Report.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.430 EMISSIONS REPORT
Section 232.430 Emissions
Report
a) On or before October 1, 1997, the owner or operator of a
source subject to this Subpart shall file an emissions report for the calendar
year 1996 which shall include the following information:
1) Source identification information and the source's actual annual
emissions of each ITAC (identified by generic name and Chemical Abstract
Service (CAS) number) expressed in tons per year (TPY), and the source's annual
fugitive emissions of each ITAC, expressed in TPY, for each ITAC that exceeds
the threshold for applicability as set forth in Section 232.410 of this Part.
In determining the actual annual emissions of each ITAC, the source may exclude
emissions of such ITAC from all emission units with de minimis emissions of
ITACs; or
2) If the owner or operator of a source subject to this Subpart
so elects, the owner or operator may choose to submit the relevant portions of
the USEPA's Emergency Planning and Community Right to Know Act (EPCRA) Form R
in lieu of the report required under subsection (a)(1) of this Section. If the
owner or operator so elects, the reporting of emissions under Form R may be
reported in pounds per year rather than in tons per year (TPY) as required in
subsection (a)(1) of this Section.
b) The following emissions of ITACs shall be considered to be de
minimis and shall not be subject to reporting requirements under this Subpart:
1) Emissions of ITACs from an emission unit which, in the
aggregate, are less than one-half (0.5) TPY;
2) Emissions from a process unit resulting from a process vent
stream with ITAC concentrations that are always less than one-tenth of one
percent (0.001) by weight on a daily basis, if such concentrations include any
carcinogen listed in Appendix C of this Part;
3) Emissions from a process unit resulting from a process vent
stream with ITAC concentrations that are always less than one percent (0.01) by
weight on a daily basis, if such concentrations do not include any carcinogen
listed in Appendix C of this Part; or
4) Fugitive emissions of ITACs from a process unit which, in the
aggregate, are less than one-half (0.5) TPY.
c) If a source becomes subject to this Subpart on or after the
effective date of this Subpart, the owner or operator of the source shall
submit an emissions report to the Agency on or before July 1 of the year
following the date the source becomes subject to this Subpart for the period
from the date the source first becomes subject to this Subpart through the end
of the calendar year before the year the first report from such source is due
under this Subpart. Such emissions report shall contain all of the information
listed in subsection (a)(1) or (a)(2) of this Section and any additional
information requested by the Agency pursuant to Section 232.450 of this Part.
Any such emissions report shall satisfy the requirements of Subpart D of this
Part.
d) An owner or operator of a source subject to this Subpart shall
submit to the Agency a revised, emissions report on or before July 1 of the
year following the occurrence of any of the following:
1) If the source's actual annual emissions of any individual ITAC
or any combination of ITACs required to be reported under this Subpart
increases by more than one-half (0.5) TPY or one (1) TPY, respectively, from
the sources' emissions of ITACs initially reported under this Subpart; or
2) If the source emits an ITAC that exceeds the threshold for
applicability as set forth in Section 232.410 of this Part which was not
previously reported in the source's initial report of its emissions of ITACs or
in any subsequent revised report of its emissions of ITACs required to be
submitted pursuant to this subsection (d).
e) Any revised emissions report required to be submitted under
subsection (d) of this Section shall contain all of the information listed in
subsection (a) of this Section and any additional information requested by the
Agency pursuant to Section 232.450 of this Part. Any revised emissions report
shall satisfy the requirements of Subpart D.
f) By July 1 of the calendar year following any modification or
change to an emission unit requiring a revision to an existing permit or a new
permit which may result in an increase in emissions of a previously reported
ITAC by ten percent (.10) or more, an owner or operator of a source subject to
this Subpart shall submit to the Agency a revised emissions report which
includes the information required under this Section 232.430.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.440 USE OF AVAILABLE DATA
Section 232.440 Use of
Available Data
a) In order to provide the information requested by the Agency
pursuant to Section 232.450 of this Part, the owner or operator of a source
may:
1) Use reasonable engineering estimates of total emissions of
individual ITACs pursuant to an emissions determination method, if, in each
case, the owner or operator of a source specifies the emissions determination
method used to estimate total emissions and certifies that such data represents
the best available information and is true and accurate to the best of his/her
knowledge; or
2) If available, use monitoring or measuring data collected
pursuant to other provisions of law or regulation.
b) Nothing in this Subpart requires the monitoring or measurement
of the quantities, concentrations, or frequency of emissions of any ITAC beyond
any monitoring or measurement required under other provisions of law or
regulation.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.450 RETENTION OF RECORDS/ADDITIONAL INFORMATION
Section 232.450 Retention of
Records/Additional Information
a) For purposes of modeling and conducting assessments of
information submitted under this Subpart, the Agency may request supporting
documentation or additional information for any emissions report submitted by a
source, including:
1) An identification by generic name and Chemical Abstract
Service (CAS) number the source's emissions of each ITAC by emission unit, with
maximum hourly emission rates in lbs/hr and actual annual emissions in TPY and
the source's fugitive emissions of each ITAC in TPY;
2) Operating data, exhaust point information and, if applicable,
control device information for each emission unit; and
3) Copies of engineering estimate calculations, mass balance
calculations, and any other information or documentation used by the owner or
operator of a source in preparing an emissions report.
b) All records and calculations upon which the data submitted in
the emissions report are based must be retained by the source for a minimum of
three (3) years following the filing of a complete report. The owner or
operator of a source shall provide the requested information in a format
acceptable to the Agency within 60 days after the receipt of the request.
c) Nothing in this Section shall be interpreted to impose upon
any source subject to this Subpart any additional monitoring which is not
otherwise required by applicable rules or a permit condition.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.460 REPORTING OF ERRORS
Section 232.460 Reporting of
Errors
If, after submitting any
emissions report required by this Subpart, the owner or operator of a source
discovers any error in the data reported, the owner or operator shall notify
the Agency of the error in writing and shall provide the Agency with the correct
data. The notification and correction shall be conveyed to the Agency within
sixty (60) days after the owner's or operator's discovery of the error. The
corrected data shall be certified in accordance with Section 232.421 of this
Part.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
SUBPART E: LISTING AND DELISTING
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.500 PROCEDURES FOR LISTING AND DELISTING TOXIC AIR CONTAMINANTS
Section 232.500 Procedures
for Listing and Delisting Toxic Air Contaminants
a) Any person may submit a regulatory proposal to the Board to
list or delist a toxic air contaminant.
b) The proposal to list a contaminant as a toxic air contaminant,
or to delist a toxic air contaminant, must include, at a minimum, the
following:
1) The contaminant or toxic air contaminant name and Chemical
Abstract Service Number where applicable;
2) The basis for listing or delisting pursuant to Section
232.200(b) or (c). This shall include but is not limited to, a showing of one
of the following:
A) The toxicity score or carcinogen classification is correctly
determined pursuant to the Subpart C procedures;
B) The Subpart C procedure for determining a toxicity score or
carcinogen classification is not appropriate for the contaminant;
C) The Subpart C procedure for determining a toxicity score or
carcinogen classification is incorrectly applied for the contaminant;
D) The studies used are inadequate for the purposes of the Subpart
C procedure; or
E) Additional or new studies should be considered in a
determination to list or delist a contaminant.
3) A copy of each study or report used to justify the proposal.
c) The Agency shall participate in each proposal to list or
delist a toxic air contaminant and must provide the Board with a recommendation
as to advisability of listing or delisting. Such recommendation must include a
toxicity scoring pursuant to Section 232.300 and a carcinogen classification
pursuant to Section 232.310.
d) The Agency will propose an update of the list of toxic air
contaminants to the Board no less frequently than once every 2 years.
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.501 LISTING OF FEDERAL HAZARDOUS AIR POLLUTANTS, GREAT LAKES COMMISSION TOXIC COMPOUNDS AND GREAT WATERS PROGRAM TOXIC COMPOUNDS
Section 232.501 Listing of
Federal Hazardous Air Pollutants, Great Lakes Commission Toxic Compounds and
Great Waters Program Toxic Compounds
Notwithstanding the provisions
of Section 232.500 of this Subpart, all chemicals listed as "hazardous air
pollutants" under Section 112(b) of the CAA (1990) (42 U.S.C. 7412(b)),
and all chemicals targeted as toxic compounds or chemicals by the Great Lakes Commission
or under the United States Environmental Protection Agency's "Great
Waters" Program which are not currently listed as toxic air contaminants
under this Part, are hereby listed as toxic air contaminants under Appendix A
of this Part. The listing of hazardous air pollutants and other toxic
compounds or chemicals as toxic air contaminants under this Section is without
reference to the listing procedures of Section 232.500 of this Subpart.
(Source: Added at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.APPENDIX A LIST OF TOXIC AIR CONTAMINANTS
Section 232.APPENDIX A List
of Toxic Air Contaminants
|
Chemical Name
|
CAS Number
|
|
|
|
|
Acetaldehyde
|
75-07-0*
|
|
Acetamide
|
60-35-5*
|
|
Acetonitrile
|
75-05-8*
|
|
Acetophenone
|
98-86-2*
|
|
2-Acetylaminofluorene
|
53-96-3*
|
|
Acrolein
|
107-02-8*
|
|
Acrylamide
|
79-06-1*
|
|
Acrylic acid
|
79-10-7*
|
|
Acrylonitrile
|
107-13-1*
|
|
Aldrin
|
309-00-2**
|
|
Allyl chloride
|
107-05-1*
|
|
2-Aminoanthraquinone
|
117-79-3
|
|
4-Aminoazobenzene
|
60-09-3
|
|
o-Aminoazotoluene
|
93-56-3
|
|
4-Aminobiphenyl
|
92-67-1*
|
|
1-Amino-2-methylanthraquinone
|
82-28-0
|
|
Amitrole
|
61-82-5
|
|
Aniline
|
62-53-3*
|
|
o-Anisidine
|
90-04-0*
|
|
o-Anisidine hydrochloride
|
134-29-2
|
|
Antimony
|
7440-36-0
|
|
Arsenic
|
7440-38-2**
|
|
Asbestos
|
1332-21-4*
|
|
Azobenzene
|
103-33-3
|
|
Benzo(a)anthracene
|
56-55-3**
|
|
Benzene
|
71-43-2*
|
|
Benzidine
|
92-87-5*
|
|
Benzo(a)pyrene
|
50-32-8**
|
|
Benzo(b)fluoranthene
[3,4-Benzofluoranthene]
|
205-99-2**
|
|
Benzo(j)fluoranthene
|
205-82-3
|
|
Benzo(k)fluoranthene
[11,12-Benzofluoranthene]
|
207-08-9**
|
|
1,12-Benzoperylene
|
191-24-2
|
|
Benzotrichloride
|
98-07-7*
|
|
Benzyl chloride
|
100-44-7*
|
|
Benzyl violet
|
1694-09-3
|
|
Beryllium
|
7440-41-7
|
|
Beryllium oxide
|
1304-56-9*
|
|
Biphenyl
|
92-52-4*
|
|
Bis(chloromethyl)ether
|
542-88-1*
|
|
Boron trifluoride
|
7637-07-2
|
|
Bromoform
|
75-25-2*
|
|
4,Bromophenyl phenyl ether
|
101-55-3**
|
|
1,3-Butadiene
|
106-99-0*
|
|
Butyl benzyl phthalate
|
85-68-7
|
|
beta-Butyrolacetone
|
3068-88-0
|
|
C.I. Basic Red 9
monohydrochloride
|
569-61-9
|
|
Cadmium
|
7440-43-9**
|
|
Cadmium oxide
|
1306-19-0*
|
|
Calcium cyanamide
|
156-62-7*
|
|
Caprolactam
|
105-60-2
|
|
Captan
|
133-06-2*
|
|
Carbaryl
|
63-25-2*
|
|
Carbofuran
|
1563-66-2
|
|
Carbon black
|
1333-86-4
|
|
Carbon disulfide
|
75-15-0*
|
|
Carbon tetrachloride
|
56-23-5++
|
|
Carbonyl sulfide
|
463-58-1*
|
|
Carbosulfan
|
55285-14-8
|
|
Catechol
|
120-80-9*
|
|
Chloramben
|
133-90-4*
|
|
Chlordane
|
57-74-9++
|
|
Chlorinated dibenzodioxins
|
--
|
|
Chlorinated dibenzofurans
|
--
|
|
Chlorendic acid
|
115-28-6
|
|
Alpha-Chlorinated toluenes
|
--
|
|
Chlorinated paraffins [C12,
60% chlorine]
|
108171-26-2
|
|
Chlorine
|
7782-50-5*
|
|
Chloroacetic acid
|
79-11-8*
|
|
2-Chloroacetophenone
|
532-27-4*
|
|
Chlorobenzene
|
108-90-7*
|
|
Chlorobenzilate
|
510-15-6*
|
|
Chloroform
|
67-66-3*
|
|
Chloromethyl methyl ether
|
107-30-2*
|
|
3,4-Chloro-2-methylpropene
|
563-47-3
|
|
4-Chloro-o-phenylenediamine
|
95-83-0
|
|
p-Chloro-o-toluidine
|
95-69-2
|
|
4-Chlorophenyl phenyl ether
|
7005-72-3**
|
|
Chloroprene
|
126-99-8*
|
|
Chromium
|
7440-47-3**
|
|
Chromium (VI)
|
18540-29-9++
|
|
Chrysene
|
218-01-9**
|
|
Coal tar (pitch) volatiles
|
65996-93-2
|
|
Cobalt
|
7440-48-4**
|
|
Coke Oven Emissions
|
--++
|
|
Copper
|
7440-50-8**
|
|
p-Cresidine
|
120-71-8
|
|
Creosote (Coal)
|
8001-58-9
|
|
Cresol (mixed isomers)
[Cresols/Cresylic acid isomers and mixture
|
1319-77-3*
|
|
o-Cresol
|
95-48-7*
|
|
m-Cresol
|
108-39-4*
|
|
p-Cresol
|
106-44-5*
|
|
Cumene
|
98-82-8*
|
|
Cyanazine
|
21725-46-2
|
|
Cyclohexanone
|
108-94-1
|
|
DDD
|
72-54-8
|
|
DDE
|
3547-04-4*
|
|
4,4'-DDE
|
72-55-9**
|
|
DDT
|
50-29-3**
|
|
Di-n-octyl phthalate
|
117-84-0**
|
|
2,4-Diaminoanisole
|
615-05-4
|
|
2,4-Diaminoanisole sulfate
|
39156-41-7
|
|
4,4'-Diaminodiphenyl ether
|
101-80-4
|
|
2,4-Diaminotoluene
|
95-80-7*
|
|
Diazomethane
|
334-88-3*
|
|
Dibenzo(a,h)acridine
|
226-36-8
|
|
Dibenzo(a,j)acridine
|
224-42-0
|
|
Dibenzo(a,h)anthracene
[1,2:5.6-Dibenzanthracene]
|
53-70-3**
|
|
Dibenzo(a,e)pyrene
|
192-65-4
|
|
Dibenzo(a,h)pyrene
|
189-64-0
|
|
Dibenzo(a,i)pyrene
|
189-55-9
|
|
Dibenzo(a,l)pyrene
|
191-30-0
|
|
Dibenzofurans
|
132-64-9*
|
|
Dibutyl phthalate
|
84-74-2++
|
|
1,2-Dibromo-3-chloropropane
|
96-12-8*
|
|
1,2-Dibromoethane [Ethylene
dibromide]
|
106-93-4*
|
|
1,4-Dichlorobenzene(p-)
|
106-46-7*
|
|
3,3'-Dichlorobenzidine
|
91-94-1*
|
|
3,3'-Dichlorobenzidine dihydrochloride
|
612-83-9
|
|
Dichloroethyl ether
[Bis(2-chloroethyl)ether]
|
111-44-4*
|
|
2,4-Dichlorophenoxyacetic acid
[2,4-D,salts and esters]
|
94-75-7*
|
|
1,2-Dichloropropane [Propylene
dichloride]
|
78-87-5*
|
|
1,3-Dichloropropylene [1,3-Dichloropropene]
|
542-75-6*
|
|
Dichlorovos
|
62-73-7*
|
|
Dieldrin
|
60-57-1**
|
|
Diepoxybutane
|
1464-53-5
|
|
Diethanolamine
|
111-42-2*
|
|
N,N-Diethyl aniline
[N,N-Dimethylaniline]
|
121-69-7*
|
|
1,2-Diethylhydrazine
|
1615-80-1
|
|
Di(2-ethylhexyl) Phthalate [Bis(2-ethylhexyl)
phthalate (DEHPI)
|
117-81-7++
|
|
Diethyl sulfate
|
64-67-5*
|
|
Diglycidyl resorcinol ether
|
101-90-6
|
|
3,3'-Dimethoxybenzidine
[Dianisidine]
|
119-90-4*
|
|
Dimethyl acetamide
|
127-19-5
|
|
Dimethyl phthalate
|
131-11-3*
|
|
4-Dimethylaminoazobenzene
[Dimethyl aminoazo- benzene]
|
60-11-7*
|
|
3,3'-Dimethylbenzidine
[o-Tolidine]
|
119-93-7*
|
|
Dimethylcarbamoyl chloride
|
79-44-7*
|
|
N,N-Dimethyl formamide
|
68-12-2*
|
|
1,1-Dimethylhydrazine
|
57-14-7*
|
|
1,2-Dimethylhydrazine
|
540-73-8
|
|
Dimethyl sulfate
|
77-78-1*
|
|
Dinitrocresol
[4,6-Dinitro-o-cresol, and salts]
|
534-52-1*
|
|
2,4-Dinitrophenol
|
51-28-5*
|
|
2,4-Dinitrotoluene
|
121-14-2*
|
|
1,4-Dioxane
[1,4-Diethyleneoxide]
|
123-91-1*
|
|
1,2-Diphenylhydrazine
|
122-66-7*
|
|
Disulfoton
|
298-04-4
|
|
Endothall
|
145-73-3
|
|
Endrin
|
72-20-8**
|
|
Epichlorohydrin
|
106-89-8*
|
|
1,2-Epoxybutane
|
106-88-7*
|
|
2-Ethoxyethanol
|
110-80-5
|
|
Ethyl acrylate
|
140-88-5++
|
|
Ethyl benzene
|
100-41-4++
|
|
Ethyl chloride [Chloroethane]
|
75-00-3*
|
|
Ethylene dichloride
[1,2-Dichloroethane]
|
107-06-2++
|
|
Ethylene glycol
|
107-21-1*
|
|
Ethyleneimine [Aziridine]
|
151-65-4*
|
|
Ethylene oxide
|
75-21-8*
|
|
Ethylene thiourea
|
96-45-7*
|
|
Ethylidene dichloride
[1,1-Dichloroethene]
|
75-34-3*
|
|
Etridiazole
|
2593-15-9
|
|
FMC-67825
|
95465-99-9
|
|
Fluorine
|
7782-41-4
|
|
Folpet
|
133-07-3
|
|
Formaldehyde
|
50-00-0*
|
|
Furmecyclox
|
60568-05-0
|
|
Heptachlor
|
76-44-8++
|
|
Heptachlor epoxide
|
1024-57-3**
|
|
Hexachlorobenzene
|
118-74-1++
|
|
Hexachloro-1,3-butadiene
[Hexachlorobutadiene]
|
87-68-3++
|
|
Hexachlorocyclopentadiene
|
77-47-4*
|
|
Hexachlorodibenzo-p-dioxin
|
19408-74-3
|
|
Hexachloroethane
|
67-72-1++
|
|
Hexamethylene-1,6-diisocyanate
|
822-06-0*
|
|
Hexamethylphosphoramide
|
680-31-9*
|
|
Hexane
|
110-54-3*
|
|
Hydrazine
|
302-01-2*
|
|
Hydrazine sulfate
|
10034-93-2
|
|
Hydrochloric acid (aerosol)
|
7647-01-0*
|
|
Hydrogen cyanide
|
74-90-8
|
|
Hydrogen fluoride
[Hydrofluoric acid]
|
7664-39-3*
|
|
Hydroquinone
|
123-31-9*
|
|
Indeno(1,2,3-cd) pyrene
|
193-39-5**
|
|
Isophorone
|
78-59-1*
|
|
Isophorone diisocyanate
|
4098-71-9
|
|
Lead
|
7439-92-1**
|
|
Lindane-[Hexachlorocyclohexane-alpha]
|
319-84-6**
|
|
Lindane-[Hexachlorocyclohexane-beta]
|
319-85-7**
|
|
Lindane-[Hexachlorocyclohexane-gamma]
[Lindane all isomers]
|
58-89-9++
|
|
Lindane-[Hexachlorocyclohexane-mixed
isomers]
|
608-73-1
|
|
Linuron
|
330-55-2
|
|
Malathion
|
121-75-5
|
|
Maleic anhydride
|
108-31-6*
|
|
Manganese
|
7439-96-5**
|
|
Mercury
|
7439-97-6**
|
|
Methanol
|
67-56-1*
|
|
Methoxychlor
|
72-43-5++
|
|
2-Methoxyethanol
|
109-86-4
|
|
2-Methoxyethanol acetate
|
110-49-6
|
|
Methyl bromide [Bromomethane]
|
74-83-9*
|
|
Methyl chloride [Chloromethane]
|
74-87-3++
|
|
Methyl chloroform
[1,1,1-Trichloroethane]
|
71-55-6++
|
|
Methyl ethyl ketone
[2-Butanone]
|
78-93-3*
|
|
Methyl isobutyl ketone
[Hexone]
|
108-10-1*
|
|
Methyl isocyanate
|
624-83-9*
|
|
Methyl methacrylate
|
80-62-6*
|
|
Methyl tert-butyl ether
|
1634-04-4*
|
|
5-Methylchrysene
|
3697-24-3
|
|
4,4'-Methylenebis(2-chloroaniline)
|
101-14-4*
|
|
Methylenebis(phenylisocyanate)
[Methylene diphenyl diisocyanate (MDI)
|
101-68-8*
|
|
4,4'-Methylenebis(N,N'-dimethyl
benzenamine)
|
101-61-1
|
|
Methylene chloride [Dichloromethane]
|
75-09-2++
|
|
4,4'-Methylenedianiline
|
101-77-9*
|
|
4,4'-Methylenedianiline
dihydrochloride
|
13552-44-8
|
|
Methyl hydrazine
|
60-34-4*
|
|
Methyl iodide [Iodomethane]
|
74-88-4*
|
|
Methyl mercaptan
|
74-93-1
|
|
N-Methyl-N'-nitro-N-nitrosoguanidine
|
70-25-7
|
|
Metolachlor
|
51218-45-2
|
|
Michler's Ketone
|
90-94-8
|
|
Mirex
|
2385-85-5**
|
|
Monoethanolamine
|
141-43-5
|
|
Naphthalene
|
91-20-3++
|
|
beta-Naphthylamide
|
91-59-8
|
|
Nickel
|
7440-02-0**
|
|
Nitric acid
|
7697-37-2
|
|
Nitrilotriacetic acid
|
139-13-9
|
|
Nitrobenzene
|
98-95-3*
|
|
4-Nitrobiphenyl
|
92-93-3*
|
|
5-Nitro-o-anisidine
|
99-59-2
|
|
2-Nitropropane
|
79-46-9*
|
|
4-Nitrophenol
|
100-02-7*
|
|
N-Nitroso-n-butyl-N-(3-carboxypropyl)
amine
|
38252-74-3
|
|
N-Nitroso-n-butyl-N-(4-hydroxybutyl)
amine
|
3817-11-6
|
|
N-Nitrosodi-n-butylamine
|
924-16-3
|
|
N-Nitrosodiethanolamine
|
1116-54-7
|
|
N-Nitrosodiethylamine
|
55-18-5
|
|
N-Nitrosodimethylamine
|
62-75-9*
|
|
N-Nitrosodiphenylamine
|
86-30-6
|
|
N-Nitrosodi-n-propylamine
|
621-64-7
|
|
N-Nitroso-N-ethylurea
|
759-73-9
|
|
3-(N-Nitrosomethylamino)
propionitrile
|
60153-49-3
|
|
N-Nitrosomethylethylamine
|
10595-95-6
|
|
N-Nitroso-N-methylurea
|
684-93-5*
|
|
N-Nitrosomethylvinylamine
|
4549-40-0
|
|
N-Nitrosomorpholine
|
59-89-2*
|
|
N-Nitrosonornicotine
|
16543-55-8
|
|
N-Nitrosopiperidine
|
100-75-4
|
|
N-Nitrosopyrrolidine
|
930-55-2
|
|
N-Nitrososarcosine
|
13256-22-9
|
|
Nitrofen
|
11836-75-5
|
|
Octachlorostyrene
|
2908-74-4**
|
|
PCDDs (Total polychlorinated
dibenzodioxins)
|
--**
|
|
PCDFs (Total polychlorinated
dibenzofurans)
|
--**
|
|
PAHs (Total polycyclic
aromatic hydrocarbons)
|
--**
|
|
Parathion
|
56-38-2++
|
|
Pentachlorobenzene
|
608-93-5**
|
|
Pentachloronitrobenzene
[Quintobenzene]
|
82-68-8++
|
|
Pentachlorophenol
|
87-86-5++
|
|
Peracetic acid
|
79-21-0
|
|
Phenol
|
108-95-2++
|
|
p-Phenylenediamine
|
106-50-3*
|
|
Phenylhydrazine
|
100-63-0
|
|
Phorate
|
298-02-2
|
|
Phosgene
|
75-44-5*
|
|
Phosphine
|
7803-51-2*
|
|
Phosphorus
|
7723-14-0*
|
|
Phosphorus oxychloride
|
10025-87-3
|
|
Phosphorus pentachloride
|
10026-13-8
|
|
Photomirex
|
39801-14-4**
|
|
Phthalic anhydride
|
85-44-9*
|
|
Polybrominated biphenyls
|
--
|
|
Polychlorinated biphenyls
[Aroclors]
|
1336-36-3++
|
|
Potassium bromate
|
7758-01-2
|
|
Propane sultone [1,3-Propane
sultone]
|
1120-71-4*
|
|
beta-Propiolactone
|
57-57-8*
|
|
Propionaldehyde
|
123-38-6*
|
|
Propoxur [Baygon]
|
114-26-1*
|
|
Propyleneimine
[1,2-Propylenimine,(2-Methy aziridine)]
|
75-55-8*
|
|
Propylene oxide
|
75-56-9*
|
|
Pyrene
|
129-00-0
|
|
Quinoline
|
91-22-5*
|
|
Quinone
|
106-51-4*
|
|
Selenium
|
7782-49-2
|
|
Sodium borate
|
1303-96-4
|
|
Styrene
|
100-42-5*
|
|
Styrene oxide
|
96-09-3*
|
|
Sulfalate
|
95-06-7
|
|
Sulfuric acid (aerosol)
|
7664-93-9
|
|
Terbufos
|
13071-79-9
|
|
1,2,3,4-Tetrachlorobenzene
|
634-66-2**
|
|
1,2,4,5-Tetrachlorobenzene
|
95-94-3**
|
|
1,1,2,2-Tetrachloroethane
|
79-34-5*
|
|
Tetrachloroethylene
[Perchloroethylene]
|
127-18-4++
|
|
2,3,7,8-Tetrachlorodibenzo-p-dioxin
[2,3,7,8-TCDD]
|
1746-01-6++
|
|
4,4'-Thiodianiline
|
139-65-1
|
|
Thiophenol
|
108-98-5
|
|
Thiourea
|
62-56-6
|
|
Thorium dioxide
|
1314-20-1
|
|
Titanium tetrachloride
|
7550-45-0*
|
|
Toluene
|
108-88-3++
|
|
Toluene-2,4-diisocyanate
[2,4-Toluene diisocyanate]
|
584-84-9*
|
|
Toluene-2,6-diisocyanate
|
91-08-7
|
|
o-Toluidine
|
95-53-4*
|
|
o-Toluidine hydrochloride
|
636-21-5
|
|
p-Toluidine
|
106-49-0
|
|
Toxaphene
|
8001-35-2++
|
|
1,2,4-Trichlorobenzene
|
120-82-1*
|
|
1,1,2-Trichloroethane
|
79-00-5*
|
|
Trichloroethylene
|
79-01-6++
|
|
2,4,5-Trichlorophenol
|
95-95-4++
|
|
2,4,6-Trichlorophenol
|
88-06-2++
|
|
Triethylamine
|
121-44-8*
|
|
Trifluralin
|
1582-09-8++
|
|
Trimethylbenzene
|
25551-13-7
|
|
1,2,4-Trimethyl benzene
|
95-63-6
|
|
2,4,6-Trinitrotoluene
|
118-96-7
|
|
2,2,4-Trimethylpentane
|
540-84-1*
|
|
Tris(2,3-dibromopropyl)
phosphate
|
126-72-7
|
|
Trypan blue
|
72-57-1
|
|
Urethane [Ethyl carbamate]
|
51-79-6*
|
|
Vinyl acetate
|
108-05-4*
|
|
Vinyl bromide
|
593-60-2*
|
|
Vinyl chloride
|
75-01-4*
|
|
Vinylidene chloride
[1,1-Dichloroethylene]
|
75-35-4*
|
|
Xylenes (isomers and mixture)
|
1330-20-7*
|
|
o-Xylenes
|
95-47-6*
|
|
m-Xylenes
|
108-38-3*
|
|
p-Xylenes
|
106-42-3*
|
|
Antimony compounds*
|
–
|
|
|
Includes any unique chemical substance
that contains antimony substance that contains antimony as part of that
chemical's infrastructure
|
|
|
|
|
|
Arsenic compounds*
|
–
|
|
|
Includes any unique chemical substance
that contains arsenic as part of that chemical's infrastructure
|
|
|
|
|
|
Beryllium compounds*
|
–
|
|
|
Includes any unique chemical substance
that contains beryllium as part of that chemical's infrastructure
|
|
|
|
|
|
Cadmium compounds*
|
–
|
|
|
Includes any unique chemical
substance that contains cadmium as part of that chemical's infrastructure
|
|
|
|
|
|
Chromium compounds*
|
–
|
|
|
Includes any unique chemical
substance that contains chromium as part of that chemical's infrastructure
|
|
|
|
|
|
Cobalt compounds*
|
|
|
|
Includes any unique chemical
substance that contains cobalt as part of that chemical's infrastructure
|
|
|
|
|
|
Cyanide compounds*
|
–
|
|
|
x(pos) CN(neg) where X =
H(pos) or any other group where a formal dissociation can be made. For
example, KCN or Ca(CN)2
|
|
|
|
|
|
Glycol ethers*
|
--
|
|
|
Includes any unique chemical
substance that contains glycol as part of that chemical's infrastructure.
Includes mono- and di- ethers of ethylene glycol, diethylene glycol, and
triethylene glycol R(OCH2CH2)n-OR' where
|
|
|
|
n=1, 2, or 3
|
|
|
|
R = alkyl or aryl groups
|
|
|
|
R' = R, H, or groups which,
when removed, yield glycol ethers with the structure: R(OCH2CH2)n-OH.
|
|
|
|
Polymers are excluded from the
glycol category.
|
|
|
|
|
|
Fine mineral fibers*
|
–
|
|
|
Includes mineral fiber
emissions from facilities manufacturing or processing glass, rock, or slag
fibers (or other mineral derived fibers) having the average diameter of 1
micrometer or less.
|
|
|
|
|
|
Lead compounds*
|
--
|
|
|
Includes any unique chemical
substance that contains lead as part of that chemical's infrastructure
|
|
|
|
|
|
Manganese compounds*
|
– ++
|
|
|
Includes any unique chemical
substance that contains manganese as part of that chemical's infrastructure
|
|
|
|
|
|
Mercury compounds*
|
–
|
|
|
Includes any unique chemical
substance that contains mercury as part of that chemical's infrastructure
|
|
|
|
|
|
Nickel compounds*
|
– ++
|
|
|
Includes any unique chemical
substance that contains nickel as part of that chemical's infrastructure
|
|
|
|
|
|
Polycyclic Organic Matter
(POM)*
|
– ++
|
|
|
Includes organic compounds
having more than one benzene ring and a boiling point equal to or greater
than 100 degrees Celsius (212 degrees Farenheit).
|
|
|
|
|
|
Radionuclides (including
radon)*
|
–
|
|
|
A type of atom which
spontaneously undergoes radioactive decay.
|
|
|
|
|
|
Selenium Compounds*
|
–
|
|
|
Includes any unique chemical
substance that contains selenium as part of that chemical's infrastructure.
|
|
|
|
|
|
* Indicates presence on HAP
List.
|
|
|
**Indicates presence on Great
Waters or Great Lakes List.
|
|
|
++=Indicates presence on HAP
and Great Waters or Great Lakes Lists.
|
|
|
|
|
|
(Source:
Amended at 21 Ill. Reg. 6237, effective May 12, 1997)
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.APPENDIX B ADDITIONAL PROCEDURES FOR CALCULATING THE CHRONIC TOXICITY SCORE
Section 232.APPENDIX B Additional
Procedures for Calculating the Chronic Toxicity Score
a) Procedures to be used in selecting chronic toxicity studies.
1) Chronic toxicity studies in which all of the items in
subsection (a)(1)(A) of this appendix are identified or measured with adequate
specificity to use the equations in subsection (b) of this appendix are to be
given first preference.
A) Study items to be identified or measured:
i) Test species;
ii) Contaminant dose;
iii) Duration of exposure must be at least 21 days, except for
developmental studies in animals, in which case the duration of exposure must
be during critical gestation days;
iv) Route of exposure; and
v) Effect of exposure.
B) In the event that two or more studies are available in which
the items in subsection (a)(1)(A) are deemed to have been identified or
measured, but which give inconsistent results, the study must be selected by
the following procedures:
i) In the event that two or more studies are laboratory animal
toxicity studies, the study that is conducted in accordance with or consistent
with Good Laboratory Practice Standards must be used. Good Laboratory Practice
Standards are incorporated by reference in Section 232.110.
ii) In the event that the application of the procedure in
subsection (i) fails to result in the selection of one study, then the study
that results in the highest Chronic Toxicity Score must be used.
2) Studies that identify or measure all of the items in
subsection (a)(1)(A) of this appendix, except for the contaminant dose, must be
given second preference.
A) For a second preference study, the Lowest Toxic Dose Score for
a given species and a given route of exposure must be determined according to
the following table:
|
Species
|
Route of Exposure
|
Lowest
Toxic Dose Score
|
|
|
|
Human
|
Inhalation
|
1
|
|
Human
|
Non-inhalation
|
⅔
|
|
Non-human
|
Inhalation
|
⅔
|
|
Non-human
|
Non-inhalation
|
⅓
|
B) In the event that two or more second preference studies are
available, the study that results in the highest Chronic Toxicity Score must be
used.
3) A contaminant for which there is insufficient data in the
study to identify the elements of either a first or second preference study
must be determined to have no data and be assigned a Chronic Toxicity Score of
0.
b) The following general equation must be used to obtain the dose
in units of milligram per kilogram per day for the oral, gavage and inhalation
routes of exposure: Dose = (I)(C)(TCF)/UF
1) For the routes of exposure listed below, use the following:
|
TCF
|
=
|
Time Correction Factor of 1,
unless the exposure was intermittent, in which case the fraction of time
during which exposure occurred is used (e.g., 5 days/week = 5/7
= 0.71).
|
|
|
|
|
|
UF
|
=
|
Uncertainty Factor of 10, used
only when data are for exposure periods less than 90 days. In the case of
fetotoxicity and teratogenicity studies, an Uncertainty Factor of 1 must be
used.
|
|
|
|
|
2) Where the exposure is oral use the following:
A) Oral Exposure via Food:
|
I
|
=
|
Food Intake in kilogram of
food ingested per kilogram of body weight per day (kg/kg-d) (refer to Chart 1
for standard values);
|
|
|
|
|
|
C
|
=
|
Contaminant Concentration in
food in units of milligram per kilogram (mg/kg); or
|
B) Oral Exposure via Water:
|
I
|
=
|
Water Intake in liter of water
ingested per kilogram of body weight per day (L/kg-d) (refer to Chart 1 for
standard values);
|
|
|
|
|
|
C
|
=
|
Contaminant Concentration in
water in units of milligram per liter (mg/L);
|
3) Where the exposure is via gavage use the following:
The product (I
X C) in the above equation must be replaced by Gavage Dose (GD) in units of
milligram of contaminant ingested per kilogram of body weight per day
(mg/kg-d); or
4) Where the exposure is via inhalation use the following:
|
I
|
=
|
Air intake in cubic meter of
air inhaled per kilogram of body weight per day (cu.m3/kg-d) measured as the
product of Ventilation Rate (VR) (refer to Chart 1 for standard values) and
Inhalation retention factor (RF) (assumed to be 0.5 for this procedure);
|
|
|
|
|
|
C
|
=
|
Contaminant Concentration in
air in units of milligram per cubic meter (mg/cu.m).
|
|
Chart
1
|
|
Summary
of Physiological Parameters
|
|
|
|
|
|
|
|
Water Intake L/kg/day
|
Food Intake kg/kg/day
|
Ventilation cu.m/kg/day
|
|
Species
|
|
|
|
|
|
|
|
|
|
Cat
|
0.100
|
0.050
|
0.46
|
|
Dog
|
0.025
|
0.025
|
0.31
|
|
Guinea Pig
|
0.075
|
0.040
|
0.58
|
|
Human
|
0.029
|
0.025
|
0.26
|
|
Monkey
|
0.14
|
0.07
|
0.32
|
|
Mouse
|
0.25
|
0.15
|
1.44
|
|
Rabbit
|
0.065
|
0.030
|
0.46
|
|
Rat
|
0.10
|
0.050
|
0.66
|
 | TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE B: AIR POLLUTION CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER f: TOXIC AIR CONTAMINANTS
PART 232
TOXIC AIR CONTAMINANTS
SECTION 232.APPENDIX C CARCINOGENS (CATEGORIES A, B1, AND B2) LISTED ON THE INTEGRATED RISK INFORMATION SYSTEM (IRIS) AS OF DECEMBER 31, 1989 (UNITED STATES ENVIRONMENTAL PROTECTION AGENCY, OFFICE OF HEALTH AND ENVIRONMENTAL ASSESSMENT)
Section 232.APPENDIX C Carcinogens
(Categories A, B1, and B2) listed on the Integrated Risk Information System
(IRIS) as of December 31, 1989 (United States Environmental Protection Agency,
Office of Health and Environmental Assessment)
|
Chemical Name
|
CAS Number
|
Category
|
|
|
|
Acetaldehyde
|
000075-07-0
|
B2
|
|
Acrylamide
|
000079-06-1
|
B2
|
|
Acrylonitrile
|
000107-13-1
|
B1
|
|
Aldrin
|
000309-00-2
|
B2
|
|
Aniline
|
000062-53-3
|
B2
|
|
Arsenic
|
007440-38-2
|
A
|
|
Azobenzene
|
000103-33-3
|
B2
|
|
Benzene
|
000071-43-2
|
A
|
|
Benzidine
|
000092-87-5
|
A
|
|
Benzo(a)pyrene
|
000050-32-8
|
B2
|
|
Benzyl chloride
|
000100-44-7
|
B2
|
|
Beryllium
|
007440-41-7
|
B2
|
|
Bis(2-ethylhexyl) phthalate
|
000117-81-7
|
B2
|
|
Bis(chloroethyl) ether
|
000111-44-4
|
B2
|
|
Bis(chloromethyl) ether
|
000542-88-1
|
A
|
|
1,3-Butadiene
|
000106-99-0
|
B2
|
|
Cadmium
|
007440-43-9
|
B1
|
|
Carbon Tetrachloride
|
000056-23-5
|
B2
|
|
Chlordane
|
000057-74-9
|
B2
|
|
Chloroform
|
000067-66-3
|
B2
|
|
Chloromethyl Methyl Ether
|
000107-30-2
|
A
|
|
Chromium(VI)
|
18540-29-9
|
A
|
|
Coke Oven Emissions
|
008007-45-2
|
A
|
|
Creosote
|
008001-58-9
|
B1
|
|
DDD
|
000072-54-8
|
B2
|
|
DDE
|
000072-55-9
|
B2
|
|
DDT
|
000050-29-3
|
B2
|
|
1,2-Dichloroethane
|
000107-06-2
|
B2
|
|
1,3-Dichloropropene
|
000542-75-6
|
B2
|
|
Dichlorovos
|
000062-73-7
|
B2
|
|
Dieldrin
|
000060-57-1
|
B2
|
|
Dimethyl Sulfate
|
000077-78-1
|
B2
|
|
1,4-Dioxane
|
000123-91-1
|
B2
|
|
1,2-Diphenylhydrazine
|
000122-66-7
|
B2
|
|
Epichlorohydrin
|
000106-89-8
|
B2
|
|
Ethylene Dibromide
|
000106-93-4
|
B2
|
|
Folpet
|
000133-07-3
|
B2
|
|
Formaldehyde
|
000050-00-0
|
B1
|
|
Furmecyclox
|
060568-05-0
|
B2
|
|
Heptachlor
|
000076-44-8
|
B2
|
|
Heptachlor Epoxide
|
001024-57-3
|
B2
|
|
Hexachlorocyclohexane, technical
|
000608-73-1
|
B2
|
|
alpha-Hexachlorocyclohexane
|
000319-84-6
|
B2
|
|
Hexachlorodibenzo-p-dioxin
|
019408-74-3
|
B2
|
|
Hydrazine, Hydrazine Sulfate
(mixture)
|
|
B2
|
|
Lead and Compounds (Inorganic)
|
|
B2
|
|
4,4'-Methylenebis(N,N'-
dimethyl) benzenamine
|
000101-61-1
|
B2
|
|
N-Nitroso-N-methylethylamine
|
010595-95-6
|
B2
|
|
N-Nitroso-di-n-butylamine
|
000924-16-3
|
B2
|
|
N-Nitrosodi-N-propylamine
|
000621-64-7
|
B2
|
|
N-Nitrosodiethanolamine
|
001116-54-7
|
B2
|
|
N-Nitrosodiethylamine
|
000055-18-5
|
B2
|
|
N-Nitrosodimethylamine
|
000062-75-9
|
B2
|
|
N-Nitrosodiphenylamine
|
000086-30-6
|
B2
|
|
N-Nitrosopyrrolidine
|
000930-55-2
|
B2
|
|
Nickel Carbonyl
|
013463-39-3
|
B2
|
|
Nickel Refinery Dust
|
007440-02-0
|
A
|
|
Nickel Subsulfide
|
012035-72-2
|
A
|
|
Polychlorinated Biphenyls
|
001336-36-3
|
B2
|
|
Toxaphene
|
008001-35-2
|
B2
|
AUTHORITY: Implementing Section 9.5 and authorized by Section 27 of the Environmental Protection Act [415 ILCS 5/9.5 and 27].
SOURCE: Adopted in R90-1 at 16 Ill. Reg. 16592, effective October 18, 1992; amended in R96-4 at 21 Ill. Reg. 6237, effective May 12, 1997; amended in R22-17 at 49 Ill. Reg. 6462, effective April 23, 2025.
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|